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ceramic is suppose to be better for heat reasons and they won't rust. I dunno much about the Stainless Steel and rusting, but I've always heard chrome headers rust like crazy. I've had SLP Ceramic LT's for a year and they look great steal.
benefits: lowers under-hood temp, long lasting shine/wont rust, improves exhaust scavenging which also helps build HP anyone today would be crazy NOT getting the HTC/Cermaic coatings on exhaust today, the +'s to the coated headers/exhaust today, far exceed the extra cost.